Comparative Corrosion Behaviour of Mild Steel and Stainless Steel in Hydrochloric and Nitric Acid Environments: Implications for Sustainable Material Use
DOI:
https://doi.org/10.24191/bioenv.v3i3.123Keywords:
Corrosion behavior , Acidic environment , Mild steel , Stainless steel , Weight loss analysisAbstract
Corrosion of structural metals in acidic environments remains a critical concern for both industrial efficiency and environmental sustainability. This study comparatively investigates the corrosion behaviour of mild steel and stainless steel in hydrochloric acid (HCl) and nitric acid (HNO₃) media at varying concentrations and immersion periods. Weight loss measurements were used to evaluate corrosion rates, supported by comparative analysis over a five-day exposure. The results revealed that corrosion rates increased with acid concentration and exposure time where HNO₃ showing stronger corrosive aggressiveness than HCl due to its oxidizing properties. Mild steel experienced significantly higher mass loss than stainless steel due to the absence of a stable passive oxide layer. A gradual reduction in corrosion rate after prolonged exposure indicated the formation of protective corrosion products that limit further dissolution. Overall, stainless steel demonstrated superior corrosion resistance under all conditions. These findings are vital for material selection in chemical and process industries, particularly where equipment is exposed to acidic effluents. Minimizing corrosion-related failures not only extends the service life of metallic components but also reduces environmental contamination and conserves metallic bioresources through more sustainable industrial practices.
References
Cheng, Z., Tan, Z., Guo, Z., Yang, J., & Wang, Q. (2020). Recent progress in sustainable and energy-efficient technologies for sinter production in the iron and steel industry. Renewable and Sustainable Energy Reviews, 131, 110034. https://doi.org/10.1016/j.rser.2020.110034
Habeeb, H. J., Luaibi, H. M., Dakhil, R. M., Kadhum, A. A. H., Al-Amiery, A. A., & Gaaz, T. S. (2018). Development of new corrosion inhibitor tested on mild steel supported by electrochemical study. Results in Physics, 8, 1260-1267. https://doi.org/10.1016/j.rinp.2018.02.015
Husaini, M., Usman, B., & Ibrahim, M. B. (2018). Evaluation of corrosion behaviour of aluminum in different environment. Bayero Journal of Pure and Applied Sciences, 11(1), 88-92. https://doi.org/10.4314/bajopas.v11i1.15S
Raschman, P., Kyslytsyna, M., Popovič, Ľ., & Sučik, G. (2024). What controls the leaching of magnesite with concentrated solutions of hydrochloric or nitric acid? Mineral Processing and Extractive Metallurgy Review, 45(8), 974-981. https://doi.org/10.1080/08827508.2024.2349127
Khamaysa, O. M. A., Selatnia, I., Lgaz, H., Sid, A., Lee, H. S., Zeghache, H., Benahmed, M., Ali, I. H., & Mosset, P. (2021). Hydrazone-based green corrosion inhibitors for API grade carbon steel in HCl: Insights from electrochemical, XPS, and computational studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 626, 127047. https://doi.org/10.1016/j.colsurfa.2021.127047
Malaret, F., & Yang, X. S. (2022). Exact calculation of corrosion rates by the weight-loss method. Experimental Results, 3, e13. https://doi.org/10.1017/exp.2022.5
Mohammed, H. K., Jafar, S. A., Humadi, J. I., Sehgal, S., Saxena, K. K., Abdullah, G. H., Saeed, L. I., Salman, M. S., & Abdullah, W. S. (2023). Investigation of carbon steel corrosion rate in different acidic environments. Materials Today: Proceedings, Available online. https://doi.org/10.1016/j.matpr.2023.03.792
Muhammad, A. A., Almula, T. A., & Sultan, D. A. (2021, August). Corrosion of carbon steel and alloy steel: effect of humidity and hydrochloric acid. IOP Conference Series: Materials Science and Engineering,1173, 01206. https://doi.org/10.1088/1757-899X/1173/1/012061
Shen, F., Liu, G., Liu, C., Zhang, Y., & Yang, L. (2024). Corrosion and oxidation on iron surfaces in chloride contaminated electrolytes: insights from ReaxFF molecular dynamic simulations. Journal of Materials Research and Technology, 29, 1305-1312. https://doi.org/10.1016/j.jmrt.2024.01.194
Othman, K. A., Hamad, W. M., & Omer, R. A. (2025). Theoretical and experimental exploration of organic molecules adsorption on iron surfaces for corrosion inhibition: a review. Corrosion Reviews, 43(3), 335-359. https://doi.org/10.1515/corrrev-2024-0039
Rana, A., & Jindal, G. (2024). A compilation of Corrosion inhibitors in acidic environments: improvements and advancements from 2018–2023. Chemical Papers, 78(11), 6241-6257. https://doi.org/10.1007/s11696-024-03503-5
Wang, X., Liu, J., Zhang, Z., Xiang, Q., Zhang, J., Chen, L., & Xie, H. (2024). Mechanism for corrosion inhibition of pure iron in 1 M HCl by Rauiella Fujisana: Experimental, GCMS, DFT, VASP and solid liquid modeling studies. Industrial Crops and Products, 207, 117692. https://doi.org/10.1016/j.indcrop.2023.117692
Widyanto, B., & Putri, S. W. S. (2019). Corrosion behavior of ASTM A1008 carbon steel in mixtures of HNO3, H2SO4, and HCl using immersion and polarization methods. Materials transactions, 60(5), 732-736. https://doi.org/10.2320/matertrans.M2018315
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Copyright (c) 2025 Muhammad Syakir Zukfli, Muhammad Nur Aidid Farihin Kashpu Anuar, Danish Haiqal Umar Dzakir , Adam Harith Noorzulan, Che Muhammad Amin Che Hamid , Ahmad Ifwad Mohamed, Muhammad Nasri, Mohammad Hafizudden Mohd Zaki

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